Analytical performances of lipophilic diamides based alkaline earth ion‐selective electrodes

Authors

Klára Tóth, Budapest University of Technology and Economics
Ernö Lindner, Budapest University of Technology and Economics
Mária Horváth, Budapest University of Technology and Economics
Judit Jeney, Budapest University of Technology and Economics
Ernö Pungor, Budapest University of Technology and Economics
István Bitter, Budapest University of Technology and EconomicsFollow
Béla Ágai, Budapest University of Technology and EconomicsFollow
László Töke, Budapest University of Technology and Economics

Abstract

Based on complex chemical considerations, lipophilic diamide derivatives have been designed and synthesized as ionophores for liquid membrane electrodes. The structure‐selectivity studies revealed that the majority of the ligands exhibit calcium ion selectivity, except the compound bis‐N,N‐dicyclohexyl‐malonamide. The latter has an almost equal selectivity for Ca2+ and Mg2+ and sufficiently rejects sodium ions, thus it lends itself to water hardness measurements. Copyright © 1993 VCH Publishers, Inc.

Publication Title

Electroanalysis

Recommended Citation

Tóth, K., Lindner, E., Horváth, M., Jeney, J., Pungor, E., Bitter, I., Ágai, B., & Töke, L. (1993). Analytical performances of lipophilic diamides based alkaline earth ion‐selective electrodes. Electroanalysis, 5 (2022-09-10), 781-790. https://doi.org/10.1002/elan.1140050911