Pd-catalyzed C-H activation/C-N bond formation: A new route to 1-aryl-1H-benzotriazoles

Authors

Rapolu Kiran Kumar, Indian Institute of Technology Guwahati
Md Ashif Ali, Indian Institute of Technology Guwahati
Tharmalingam Punniyamurthy, Indian Institute of Technology Guwahati

Abstract

A method for the C-H activation of aryl triazene compounds followed by intramolecular amination is described. It involves the use of a catalytic amount of Pd(OAc)2 that efficiently effects the cyclization to provide 1-aryl-1H-benzotriazoles at moderate temperature. © 2011 American Chemical Society.

Publication Title

Organic Letters

Recommended Citation

Kumar, R., Ali, M., & Punniyamurthy, T. (2011). Pd-catalyzed C-H activation/C-N bond formation: A new route to 1-aryl-1H-benzotriazoles. Organic Letters (8), 2102-2105. https://doi.org/10.1021/ol200523a