Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte)
Abstract
The quaternary ammonium salt, N,N-diallyl-N-carboethoxymethyl-N- carbomethoxypentylammonium chloride 13, on polymerization in aqueous solution using tert-butylhydroperoxide, afforded the polyelectrolyte 14. The copolymer 15 of the monomer 13 and sulfur dioxide was synthesized in excellent yield. The polyelectrolytes 14 and 15 on acidic hydrolysis gave the poly(ampholyte-electrolytes) 16 and 17 which contain structural features common to both polyampholytes and conventional polyelectrolytes. The solution properties of these polymers are discussed in detail. The poly(ampholyte-electrolyte)s, 16 and 17 are shown to have considerably higher viscosity than their corresponding polyelectrolytes 14 and 15. (C) 2000 Elsevier Science Ltd. All rights reserved.
Publication Title
Polymer
Recommended Citation
Ali, M., Perzanowski, H., & Ali, S. (2000). Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte). Polymer (15), 5591-5600. https://doi.org/10.1016/S0032-3861(99)00764-8
