Asymmetric transfer hydrogenation over Ru-TsDPEN catalysts supported on siliceous mesocellular foam

Authors

Xiaohua Huang, Massachusetts Institute of Technology
Stephen L. Buchwald, Massachusetts Institute of Technology

Abstract

Equation presented LiN(SiMe3)2, Ph3SiNH2, and LiNH2 can be be used as ammonia equivalents for the Pd-catalyzed coupling of aryl halides. Using these amine derivatives, simple anilines, including ortho-substituted ones, as well as di-and triarylamines can be readily prepared.

Publication Title

Chemical Communications

Recommended Citation

Huang, X., & Buchwald, S. (2007). Asymmetric transfer hydrogenation over Ru-TsDPEN catalysts supported on siliceous mesocellular foam. Chemical Communications (18), 1825-1827. https://doi.org/10.1039/b615564b