Facile Separations of Enantiomers of Chiral Organometallic Compounds with a Bakerbond Chlralcel HPLC Column

Authors

James A. Ramsden, The University of Utah
Charles M. Garner, The University of UtahFollow
J. A. Gladysz, The University of Utah

Abstract

Enantiomers of 22 compounds of the formula (η6-C5R5)M(L)(PAr3)(X) (M/L = Re/NO, Fe/CO) are separated under the title conditions (hexane/2-propanol). In each case, theoretical plate numbers, capacity factors, separation factors, and resolution are determined. Trends in these data and compounds for which enantiomers are not resolved are discussed. © 1991, American Chemical Society. All rights reserved.

Publication Title

Organometallics

Recommended Citation

Ramsden, J., Garner, C., & Gladysz, J. (1991). Facile Separations of Enantiomers of Chiral Organometallic Compounds with a Bakerbond Chlralcel HPLC Column. Organometallics, 10 (5), 1631-1633. https://doi.org/10.1021/om00051a066