Title

Facile Separations of Enantiomers of Chiral Organometallic Compounds with a Bakerbond Chlralcel HPLC Column

Abstract

Enantiomers of 22 compounds of the formula (η6-C5R5)M(L)(PAr3)(X) (M/L = Re/NO, Fe/CO) are separated under the title conditions (hexane/2-propanol). In each case, theoretical plate numbers, capacity factors, separation factors, and resolution are determined. Trends in these data and compounds for which enantiomers are not resolved are discussed. © 1991, American Chemical Society. All rights reserved.

Publication Title

Organometallics

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