Rearrangement of η⁵-CpMn(CO)2(HSiEt3): A Missing Step in the Energy Surface for the Oxidative Addition of Silane to CpMn(CO)2(heptane)

Authors

Songnan Hu, University of Memphis
Gerard J. Farrell, University of MemphisFollow
Charles Cook, University of Memphis
Randy Johnston, University of Memphis
Theodore J. Burkey, University of Memphis

Abstract

The rearrangement of a triethylsilane adduct with η5-CpMn(CO)2 has been detected by photoacoustic calorimetry. The energetics and kinetics of this process in neat triethylsilane, heptane, and perfluorodecalin are reported. © 1994, American Chemical Society. All rights reserved.

Publication Title

Organometallics

Recommended Citation

Hu, S., Farrell, G., Cook, C., Johnston, R., & Burkey, T. (1994). Rearrangement of η⁵-CpMn(CO)2(HSiEt3): A Missing Step in the Energy Surface for the Oxidative Addition of Silane to CpMn(CO)2(heptane). Organometallics, 13 (11), 4127-4128. https://doi.org/10.1021/om00023a001