Title

Rearrangement of η5-CpMn(CO)2(HSiEt3): A Missing Step in the Energy Surface for the Oxidative Addition of Silane to CpMn(CO)2(heptane)

Abstract

The rearrangement of a triethylsilane adduct with η5-CpMn(CO)2 has been detected by photoacoustic calorimetry. The energetics and kinetics of this process in neat triethylsilane, heptane, and perfluorodecalin are reported. © 1994, American Chemical Society. All rights reserved.

Publication Title

Organometallics

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